69261-50-3

Basic information

• Product Name: N-(benzyloxycarbonyl)acetamide
• Synonyms: N-(benzyloxycarbonyl)acetamide
• CAS NO: 69261-50-3
• Molecular Weight: 193.202
• Mol File: 69261-50-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: N-(benzyloxycarbonyl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(benzyloxycarbonyl)acetamide(69261-50-3)
• EPA Substance Registry System: N-(benzyloxycarbonyl)acetamide(69261-50-3)

Safety Data

• Hazardous Substances Data: 69261-50-3(Hazardous Substances Data)

Upstream product

• 621-84-1 O-benzyl carbamate 
• 75-36-5 acetyl chloride 
• 108-24-7 acetic anhydride 
• 4132-86-9 N-benzyloxycarbonylalanine 
• 1142-20-7 N-Cbz-Ala 

Downstream Products

• 80662-87-9 3-(((benzyloxy)carbonyl)amino)propyl acetate 
• 122313-52-4 benzyl N-(1-methoxyethyl)carbamate 

Relevant articles and documents

Oxidative photo-decarboxylation in the presence of mesoporous silicas

FSM-16, a mesoporous silica, was found to catalyze oxidative photo-decarboxylation of α-hydroxy carboxylic acid, phenyl acetic acid derivatives and N-acyl-protected α-amino acids to afford the corresponding carbonyl compounds. Furthermore, FSM-16 proved to be re-usable by re-calcination at 450°C after the reaction.

SALT OF ISOLATED COMPOUND CONTAINING AMIDE GROUP, METHOD FOR PRODUCING THE SAME, AND METHOD FOR SYNTHESIZING AMIDE COMPOUND USING THE SAME

PROBLEM TO BE SOLVED: To provide a salt of an isolated compound containing an amide group, a method for producing the same, and a method for synthesizing an amide compound using the same. SOLUTION: The present invention provides a salt of an isolated compound containing an amide group represented by formula (1) (M is an element belonging to group 1 in the periodic table; P is a first protective group of an amine represented by R1-O(C=O)-; Q is a second protective group of an amine represented by R2-(C=O)-; R1 and R2 independently represent a substituted/unsubstituted hydrocarbon group). SELECTED DRAWING: None COPYRIGHT: (C)2018,JPOandINPIT

Short communication: Silica sulfuric acid: A versatile and reusable heterogeneous catalyst for the synthesis of N-ACYL carbamates and oxazolidinones under solvent-free conditions

Silica sulfuric acid catalyzes efficiently the reaction of carbamates and oxazolidinones with anhydrides under solvent-free conditions. All the reactions were done at room temperature and the N-acyl carbamates and oxazolidinones were obtained with high yi