6928-77-4

Basic information

• Product Name: DIBENZYLMAGNESIUM
• Synonyms: DIBENZYLMAGNESIUM
• CAS NO: 6928-77-4
• Molecular Formula: C₁₄H₁₄Mg
• Molecular Weight: 206.56596
• Mol File: 6928-77-4.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: DIBENZYLMAGNESIUM(CAS DataBase Reference)
• NIST Chemistry Reference: DIBENZYLMAGNESIUM(6928-77-4)
• EPA Substance Registry System: DIBENZYLMAGNESIUM(6928-77-4)

Safety Data

• Hazardous Substances Data: 6928-77-4(Hazardous Substances Data)

Upstream product

• 6921-34-2 benzylmagnesium chloride 
• 100-39-0 benzyl bromide 
• 7439-95-4 magnesium 
• 100-44-7 benzyl chloride 

Downstream Products

• 4403-73-0 benzylsulfinic acid 
• 120698-24-0 2-benzyl-4-phenyl-pyridine 
• 205697-90-1 [p-Bu(t)-calix[4]-(OMe)2(O)2Ti(CH₂Ph)] 
• 205697-93-4 [p-Bu(t)-calix[4]-(OMe)(O)3Ti(CH₂Ph)] 
• 425408-22-6 [W(CH2C6H5)(η3-C3H5)(CO)2(phen)] 
• 108-88-3 toluene 
• 1422360-46-0 fac-chromium tri(benzyl)tris(tetrahydrofuran) 

Relevant articles and documents

Symmetric diarylsulfoxides as asymmetric sulfinylating reagents for dialkylmagnesium compounds

At -78 °C, primary dialkylmagnesium compounds reacted with diarylsulfoxides when 1.5 equiv of the dilithium salt of (S)-BINOL was added as a promotor. Alkyl aryl sulfoxides resulted in up to quantitative yield and with up to 97% ee. This demonstrates the feasibility of asymmetric sulfinylations by achiral sulfinylating agents (from the perspective of Alkyl2Mg) as well as the feasibility of asymmetric sulfoxide-magnesium exchanges (from the perspective of Ar2SO).