69392-05-8Relevant academic research and scientific papers
Radical rearrangements of α-Iodoalkyl phenyl sulfones involving 1,5 hydrogen atom transfer reactions
Masnyk, Marek
, p. 879 - 882 (2007/10/03)
α-Iodoalkyl phenyl sulfones undergo radical rearrangement to 5-iodo-1-phenylsulfanyl derivatives when heated with benzoyl peroxide or when irradiated with a sunlamp in the presence of hexabutylditin. Products of these rearrangements, upon treatment with bases, can be easily and stereoselectively converted into trans phenylsulfonyl derivatives of cyclopentane.
