69396-90-3Relevant academic research and scientific papers
Efficient combination of task-specific ionic liquid and microwave dielectric heating applied to synthesis of a large variety of nitrones
Valizadeh, Hassan
experimental part, p. 78 - 83 (2011/04/16)
Under mild microwave irradiation conditions and without any additional organic solvents, a large variety of nitrones were prepared in a weak Lewis base phosphinite task-specific ionic liquid (TSILOPPh2) in excellent yields. This catalytic TSIL was also re
Oxidation of sulfides to sulfoxides with 3-aryl-2-tert-butyloxaziridines under high pressure
Shimizu, Masao,Shibuya, Isao,Taguchi, Yoichi,Hamakawa, Satoshi,Suzuki, Kunio,Hayakawa, Takashi
, p. 3491 - 3492 (2007/10/03)
3-Phenyl-2-tert-butyloxaziridine has been shown to behave as an oxidant under 800 MPa at 100°C to oxidize sulfides to sulfoxides, in spite of having been reported to be inactive as an oxidant and to undergo thermal rearrangement to W-tert-butyl-α-phenylnitrone at atmospheric pressure. It has been shown that under thermal and high-pressure conditions the ability of the oxaziridine to react changes dramatically. The mechanism for the high-pressure reaction is also discussed.
