694-90-6

Basic information

• Product Name: 2-BROMOBICYCLO[2.2.1]HEPT-2-ENE
• Synonyms: Bicyclo[2.2.1]hept-2-ene, 2-bromo-
• CAS NO: 694-90-6
• Molecular Formula: C₇H₉Br
• Molecular Weight: 173.05
• Mol File: 694-90-6.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: 2-BROMOBICYCLO[2.2.1]HEPT-2-ENE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-BROMOBICYCLO[2.2.1]HEPT-2-ENE(694-90-6)
• EPA Substance Registry System: 2-BROMOBICYCLO[2.2.1]HEPT-2-ENE(694-90-6)

Safety Data

• Hazardous Substances Data: 694-90-6(Hazardous Substances Data)

Usage

General Description

2-Bromobicyclo[2.2.1]hept-2-ene is a chemical compound with the molecular formula C7H9Br. It is a brominated bicyclic hydrocarbon that is used in organic synthesis and as a reagent in various chemical reactions. The compound is characterized by its bicyclic structure, which makes it a valuable building block in the production of other organic compounds. It is important to handle this chemical with caution, as it is considered to be hazardous to the environment and human health. 2-Bromobicyclo[2.2.1]hept-2-ene is typically stored and used in a controlled environment to prevent any potential risks associated with its handling and use.

Upstream product

• 497-38-1 Norbornan-2-on 
• 498-66-8 norborn-2-ene 
• 75267-72-0 2,3-dibromobicyclo[2.1.1]hept-2-ene 
• 85202-08-0 2,2-dibromobicyclo<2.2.1>heptane 
• 2843-42-7 2-exo,3-endo-dibromonorbornane 
• 32346-69-3 1R(S),2S(R),4S(R),7R(S)-2,7-dibromobicyclo[2.2.1]heptane 

Downstream Products

• 4237-08-5 2-phenylnorborn-2-ene 

Relevant articles and documents

An efficient protocol for the synthesis of brominated norbornene, norbornadiene, and benzonorbornadiene

An efficient protocol for the synthesis of 2-bromonorbornene, 2-bromonorbornadiene, 2-bromoben- zonor-bornadiene, 2,3-dibromonorbornene, 2,3-dibromonorbornadiene, and 2,3-dibromobenzonorbornadiene in good yields has been developed. 1,2-Dibromotetrachloroethane is used as the brominating agent for these reactions. The results are discussed in comparison with alternative methods in the literature.

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Palladium-catalyzed hydrophenylation of bicyclic alkenes

Palladium-catalyzed hydrophenylation reactions of bicyclic alkenes were investigated. These reactions were found to be completely chemo- and stereoselective, giving only exo products on the less substituted double bonds of bicyclic alkenes in moderate to good yields. For unsymmetrical bicyclic alkenes, regioselectivities of 52:48 to 100:0 were observed with various substituents on the bicyclic alkenes.

DEOXYGENATION OF ALDEHYDES AND KETONES; A NEW GENERAL REACTION OF DIBROMOCARBENE AND DIBROMOCARBONYL YLIDES

The treatment of a variety of aldehydes and ketones with phenyl(tribromomethyl)mercury results in the production of carbon monoxide from the deoxygenation of the carbonyl group by dibromocarbene.