69434-38-4

Basic information

• Product Name: Benzoic acid (4R,5R)-5-hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester
• CAS NO: 69434-38-4
• Molecular Weight: 266.294
• Mol File: 69434-38-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzoic acid (4R,5R)-5-hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (4R,5R)-5-hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester(69434-38-4)
• EPA Substance Registry System: Benzoic acid (4R,5R)-5-hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester(69434-38-4)

Safety Data

• Hazardous Substances Data: 69434-38-4(Hazardous Substances Data)

Upstream product

• 613-90-1 benzoyl cyanide 
• 73346-74-4 (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-dimethanol 
• 3969-84-4 3,4-di-O-isopropylidene-D-mannitol 
• 3969-59-3 mannitol triacetonide 

Downstream Products

• 81546-82-9 9-((2S,3S)-threo-2,3-O-isopropylidene-4-O-p-toluenesulfonyl-2,3,4-trihydroxybutyl)adenine 
• 69434-40-8 (4R,5R)-2,2-dimethyl-4-benzoyloxymethyl-5-p-toluenesulfonyloxymethyl-1,3-dioxolane 

Relevant articles and documents

On the chemoselectivity and mechanism of desilylation of tert- butyldimethylsilyl ethers with TMSOTf

A modified literature procedure is presented for desilylating primary and secondary tert-butyldimethylsilyl ethers involving TMSOTf followed by breakdown of the bis-silyloxonium ion in methanol. The chemoselectivity of the process with respect to TBDPS, T