69441-16-3Relevant academic research and scientific papers
Molecular dynamics in solid bis(η-arene)molybdenum complexes studied by solid-state deuterium nuclear magnetic resonance spectroscopy
O'Hare, Dermot,Heyes, Stephen J.,Barlow, Stephen,Mason, Susan
, p. 2989 - 2993 (2007/10/03)
Variable-temperature solid-state 2H NMR spectra have been recorded on microcrystalline samples of [Mo(η-C6D6)2], [Mo{η-C6D3(CD3)3-1,3,5} 2] and [ZrS2/
Preparative supercritical deuterium exchange in arenes and heteroarenes
Junk, Thomas,Catallo, W. James
, p. 3445 - 3448 (2007/10/03)
Deuterated homo- and heterocyclic aromatic substrates bearing various functionalities were prepared by isotope exchange in supercritical deuterium oxide, with little or no formation of byproducts. Equilibration was attained rapidly (1-24 hrs), and deuterium exchange extended to alpha positions of alkyl homologs. Nitro- and haloarenes, thioethers, telluroethers, and some heterocyclic substrates were unstable.
