69448-04-0

Basic information

• Product Name: (dichloro-2,3cyclohexenyl-6)acete de methyle
• CAS NO: 69448-04-0
• Molecular Weight: 223.099
• Mol File: 69448-04-0.mol

Chemical Properties

• CAS DataBase Reference: (dichloro-2,3cyclohexenyl-6)acete de methyle(CAS DataBase Reference)
• NIST Chemistry Reference: (dichloro-2,3cyclohexenyl-6)acete de methyle(69448-04-0)
• EPA Substance Registry System: (dichloro-2,3cyclohexenyl-6)acete de methyle(69448-04-0)

Safety Data

• Hazardous Substances Data: 69448-04-0(Hazardous Substances Data)

Upstream product

• 78002-47-8 acides(dichloro-6,6-bicyclo<3.1.0>hexyl-2)acetiques 
• 186581-53-3 diazomethane 
• 69448-00-6 acide(dichloro-2,3cyclohexenyl-6)acetique 
• 20006-86-4 (cyclopentenyl-3)acetate de methyle 
• 78002-45-6 (dichloro-6,6 bicyclo<3.1.0>hexyl-2)acetates de methyle 
• 78002-47-8 ((1R,2R,5S)-6,6-Dichloro-bicyclo[3.1.0]hex-2-yl)-acetic acid 
• 78002-59-2 γ-lactone de l'acide(chloro-2hydroxy-3cyclohexenyl-4)acetique-cis 
• 69448-02-8 (dichloro-2,3cyclohexenyl-4)acete de methyle-trans 
• 69448-02-8 (dichloro-2,3cyclohexenyl-4)acete de methyle 
• 78002-58-1 (chloro-2hydroxy-3cyclohexenyl-4)acetate de methyle-cis 
• 69448-04-0 (dichloro-2,3-cyclohexenyl-6)acetate de methyle 
• 78002-45-6 ((1R,2R,5S)-6,6-Dichloro-bicyclo[3.1.0]hex-2-yl)-acetic acid methyl ester 

Downstream Products

• 78002-59-2 γ-lactone de l'acide(chloro-2hydroxy-3cyclohexenyl-4)acetique-cis 
• 69448-04-0 (dichloro-2,3cyclohexenyl-6)acete de methyle 
• 69448-02-8 (dichloro-2,3cyclohexenyl-4)acete de methyle 
• 69448-02-8 (dichloro-2,3cyclohexenyl-4)acete de methyle-trans 

Relevant articles and documents

Ouverture de dichlorocyclopropanes en presence d'un nucleophile interne. Absence de participation intramoleculaire. Rearrangement concerte en chlorures allyliques

It is shown that a conveniently placed internal nucleophile (carboxyl group) is not involved with the rearrangement of a diclorocyclopropane into an allylic chloride.This result appears to support a concerted mechanism of a ?s2 + ?a2 type for this rearrangement.In the products obtained, the allylic chloride may undergo displacement either by solvent (H2O), leading to alcohols, or by the internal carboxyl group, leading to a lactone.