69460-42-0Relevant academic research and scientific papers
Reactions of (RP)- and (SP)-tert-butylphenylphosphinobromidates and tert-butylphenylthionophosphinochloridates with heteroatom nucleophiles; preparation of P-chiral binol phosphinates and related compounds
Au-Yeung, Tin-Lok,Chan, Ka-Yee,Chan, Wai-Kuen,Haynes, Richard K.,Williams, Ian D.,Yeung, Lam Lung
, p. 453 - 456 (2007/10/03)
Reaction of (RP)- and (SP)-tert-butylphenylphosphinobromidates and tert-butylphenylthionophosphinochloridates with metallated phenol and BINOL alkoxides, thioalkoxides, amides and enolates leading with clean inversion at phosphorus t
New procedures for the resolution of chiral tert-butylphenylphosphine oxide and some of its reactions
Drabowicz, Joezef,Lyzwa, Piotr,Omelanczuk, Jan,Pietrusiewicz, K. Michal,Mikolajczyk, Marian
, p. 2757 - 2763 (2007/10/03)
Racemic t-butylphenylphosphine oxide was resolved via formation of diastereoisomeric complexes with (+)-(R)-1,1'-binaphthalene-2,2'-diol and (+)-(S)-mandelic acid. With the latter complexing agent, separation of the essentially enantiopure (-)-(S)-enantio
Reaction of Thiolo and Selenolo Esters of Phosphorus Acids with Halogens. Part 2. Interaction of S-Methyl t-Butyl(phenyl)- and Di-t-butyl-phosphinothiolates with Elemental Bromine and Iodine
Krawiecka, Bozena,Wojna-Tadeusiak, Elzbieta
, p. 301 - 309 (2007/10/02)
The reaction of S-methyl t-butyl(phenyl)- and di-t-butyl-phosphinothiolates with bromine and iodine involves the transient formation of the same type of halosulphonium salts, ButRP(O)S+(X)MeX- and phosphonium salts, Busup
Reaction of Thiolo and Seleno Esters of Phosphorus Acids with Halogens. 1. Stereochemical and 31P NMR Studies of Reaction of S-Methyl tert-Butylphenylphosphinothiolate with Elemental Chlorine and Sulfuryl Chloride
Krawiecka, B.,Michalski, J.,Wojna-Tadeusiak, E.
, p. 4201 - 4208 (2007/10/02)
Reaction of S-methyl tert-butylphenylphosphinothiolate (4) with elemental chlorine and sulfuryl chloride involves chlorolysis of the P-S bond and formation of the tert-butylphenylphosphinochloridate 5.It is demonstrated here that the stereoselectivity of
