695177-08-3

Upstream product

• 695177-27-6 2-((2S,4R,6S)-6-Methyl-2-phenyl-[1,3]dioxan-4-yl)-ethanol 
• 71172-20-8 diethyl (2-morpholin-4-yl-2-oxoethyl)phosphonate 
• 188924-70-1 ((2S,4S,6S)-6-Methyl-2-phenyl-[1,3]dioxan-4-yl)-acetaldehyde 

Downstream Products

• 695177-10-7 ethyl (Z)-4-[(2R,4R,6R)-6-[[(2S,4S,6S)-6-methyl-2-phenyl-1,3-dioxan-4-yl]methyl]-2-phenyl-1,3-dioxan-4-yl]-2-butenoate 
• 695177-30-1 (3S,5R)-3,5-Dihydroxy-6-((2S,4R,6S)-6-methyl-2-phenyl-[1,3]dioxan-4-yl)-hexanoic acid ethyl ester 
• 695177-29-8 ethyl (4R,5S)-4,5-epoxy-6-[(2S,4R,6S)-6-methyl-2-phenyl-1,3-dioxan-4-yl]-3-oxohexanoate 
• 549513-47-5 ethyl (2S,4S,6S)-6-[[(2S,4S,6S)-6-methyl-2-phenyl-1,3-dioxan-4-yl]methyl]-2-phenyl-1,3-dioxane-4-acetate 
• 549513-49-7 6-(6-methyl-2-phenyl-[1,3]dioxan-4-ylmethyl)-2-phenyl-[1,3]dioxan-4-yl-acetaldehyde 
• 695177-09-4 4-[(2R,3S)-2,3-epoxy-4-[(2S,4R,6S)-6-methyl-2-phenyl-1,3-dioxan-4-yl]-1-oxobutyl]morpholine 

Relevant academic research and scientific papers

Strategy for Enantio- and Diastereoselective Syntheses of All Possible Stereoisomers of 1,3-Polyol Arrays Based on a Highly Catalyst-Controlled Epoxidation of α,β-Unsaturated Morpholinyl Amides: Application to Natural Product Synthesis

We describe a new strategy for enantio- and diastereoselective syntheses of all possible stereoisomers of 1,3-polyol arrays. This strategy relies on a highly catalyst-controlled epoxidation of α,β-unsaturated morpholinyl amides promoted by the Sm-BINOL-Ph