6952-10-9Relevant academic research and scientific papers
New and efficient synthesis of CpRe(CO)3 substituted steroids
Le Bideau, Franck,Pérez-Luna, Alejandro,Marrot, Jér?me,Rager, Marie-No?lle,Stéphan, Elie,Top, Siden,Jaouen, Gérard
, p. 3939 - 3944 (2001)
Fulvenes generated from steroids have been efficiently engaged in a process implying nucleophilic or basic attack followed by a transmetallation reaction in the presence of BrRe(CO)5 to afford the corresponding CpRe(CO)3 substituted compounds. This new strategy is of relevant interest for the synthesis of new potential radiopharmaceuticals.
