69520-13-4Relevant articles and documents
Photoredox-Catalyzed Hydrosulfonylation of Arylallenes
Detistova, Galina I.,Festa, Alexey A.,Rybakov, Victor B.,Storozhenko, Olga A.,Van Der Eycken, Erik V.,Varlamov, Alexey V.,Voskressensky, Leonid G.
, (2020)
(Het)Arylallenes undergo hydrosulfonylation under photoredox-catalyzed conditions. The reaction gives vinyl sulfones in a regio- and diastereoselective manner, employing sodium sulfinates as the sulfonyl source and eosin Y as the photocatalyst. Indol-1-yl, pyrrol-1-yl, phenyl, and naphtylallenes might be used. Aliphatic allenes are incompatible with the reaction conditions.
Palladium-catalyzed coupling of vinyl tosylates with arylsulfinate salts
Reeves, Diana C.,Rodriguez, Sonia,Lee, Heewon,Haddad, Nizar,Krishnamurthy, Dhileep,Senanayake, Chris H.
experimental part, p. 2870 - 2873 (2009/09/06)
The first palladium-catalyzed coupling of vinyl tosylates with arylsulfinate salts is described. A variety of cyclic and acyclic vinyl tosylates were coupled with aryl sulfinate salts using 2.5 mol % Pd2(dba)3/5.0 mol % XantPhos to g