695200-10-3Relevant academic research and scientific papers
Synthesis and properties of a new class of nitrogen-rich multinuclear[m.n] ferrocenophanes
Tarraga, Alberto,Oton, Francisco,Espinosa, Arturo,Velasco, M. Desamparados,Molina, Pedro,Evans, David J.
, p. 458 - 459 (2004)
The synthesis of the first tetraaza[3,3]ferrocenophane, from the previously unreported 1,1′-bis(triphenylphosphoranylidenamino)ferrocene and its conversion into a nitrogen-rich [2,2]bis-[3,3]ferrocenophane is described. The electronic behaviour of these multinuclear ferrocenophanes indicates a strong electronic coupling between the iron centers.
Synthesis, structure, and properties of a mononuclear ferrocenophane bearing two carbodiimide units as bridges
Sola, Antonia,Orenes, Raúl A.,Tárraga, Alberto,Molina, Pedro
, p. 1048 - 1052 (2016)
A novel bis(carbodiimido)[11]ferrocenophane was synthesized using a methodology involving an aza, Wittig reaction of the 1,1′-bis(triphenylphosphoranylideneamino)ferrocene with the commercially available 1,3-bis(2-isocyanatopropan-2-yl)benzene. Moreover, its electrochemical and chemical properties were also examined. The ureido derivative formed when the bis(carbodiimido)ferrocenophane was hydrolyzed under acidic conditions, behaves as a chemodosimeter for sensing nitrite anions in aqueous solutions.
Ferrocene-bis(phosphinimine) Nickel(II) and Palladium(II) Alkyl Complexes: Influence of the Fe-M (M = Ni and Pd) Interaction on Redox Activity and Olefin Coordination
Abubekerov, Mark,Khan, Saeed I.,Diaconescu, Paula L.
supporting information, p. 4394 - 4402 (2017/12/05)
The synthesis of several novel nickel(II) and palladium(II) ferrocene-bis(phosphinimine) alkyl complexes containing iron-nickel and iron-palladium interactions is reported. The redox behavior of all complexes was evaluated electrochemically and chemically
1,1′-Bis(phosphoranylidenamino)ferrocene palladium(II) complexes: An unusual case of dative Fe → Pd bonding
Metallinos, Costa,Tremblay, Deanna,Barrett, Fred B.,Taylor, Nicholas J.
, p. 2044 - 2047 (2007/10/03)
Subtle differences in the electron-richness of nitrogen atoms in 1,1′-bis(phosphoranylidenamino)ferrocenes can change the coordination geometry of their palladium(II) complexes from cis to trans. Trans complexation results in concomitant formation of a relatively short dative Fe-Pd bond of 2.67 ?.
