887925-59-9Relevant academic research and scientific papers
1,1′-Bis(phosphoranylidenamino)ferrocene palladium(II) complexes: An unusual case of dative Fe → Pd bonding
Metallinos, Costa,Tremblay, Deanna,Barrett, Fred B.,Taylor, Nicholas J.
, p. 2044 - 2047 (2006)
Subtle differences in the electron-richness of nitrogen atoms in 1,1′-bis(phosphoranylidenamino)ferrocenes can change the coordination geometry of their palladium(II) complexes from cis to trans. Trans complexation results in concomitant formation of a relatively short dative Fe-Pd bond of 2.67 ?.
