695202-97-2Relevant academic research and scientific papers
Formation of an iron(II) carbene-thiolato complex by insertion of carbon monoxide into an Si-C bond
Yuki, Masahiro,Matsuo, Tsukasa,Kawaguchi, Hiroyuki
, p. 1404 - 1407 (2007/10/03)
Fischer carbenes - a new angle: The insertion of carbon monoxide into an Si-C bond of the FeII complex 1, which contains a tripodal thiolato ligand (see scheme), yields the Fischer carbene-thiolato complex 2, whose molecular structure reveals the presence of a bonding interaction between the carbene carbon atom and the thiolato sulfur atoms.
