69529-90-4

Upstream product

• 73281-90-0 methyl 4-chlorophenylsulfinylacetate 

Downstream Products

• 137821-28-4 (1S,2R)-2-phenylcyclohexanyl (R)-4-chlorophenylsulfinylacetate 
• 137761-04-7 (1R,2S,5R)-8-phenylmenthyl (R)-4-chlorophenylsulfinylacetate 

Relevant academic research and scientific papers

Biocatalytic Resolutions of Sulfinylalkanoates: A Facile Route to Optically Active Sulfoxides

Two methods are presented for kinetic resolutions of compounds containing ester and sulfoxide functionalities (sulfinylalkanoates).In the first a crude lipase preparation from Pseudomonas sp. (K 10) mediates enantioselective hydrolysis of these esters in

A FACILE ROUTE TO HOMOCHIRAL SULFOXIDES

Biocatalytic resolution of methyl sulfinylacetates afford sulfoxides (R)-(1)-(6) in very high optical yields; the products have been used in a systematic study of the "SPAC" reaction, an asymmetric synthesis of γ-hydroxy-α,β-unsaturated esters.