69533-68-2Relevant articles and documents
Microwave-assisted novel stereoselective synthesis of bis-β-lactams with 2,7-phenanthrenyl imines
Yadav, Ram Naresh,Banik, Indrani,Banik, Bimal Krishna
, p. 1377 - 1380 (2020/06/27)
Microwave-induced stereoselective synthesis of novel bis-β-lactams substituted at the 2,7 position of the phenanthrene has been performed via ketene-imine [2+2] cycloaddition reaction.
Effects of additional linkers in biphenyl-4,4′-dinitrene on the low-lying singlet-triplet energy gap and zero-field splitting
Nimura,Kikuchi,Ohana,Yabe,Kondo,Kaise
, p. 2083 - 2088 (2007/10/03)
Perturbation effects of additional linkers on the spin-spin coupling in biphenyl-4,4′-dinitrene (1) were examined by introducing a linking group between 2- and 2′-positions of 1. Five different doubly linked systems showed triplet ESR spectra corresponding to quinonoid dinitrenes. Curie law analyses suggested that all those triplet states were thermally excited triplet states. In addition, the singlet-triplet energy gaps, which were determined by the Curie law analyses, were well correlated with their corresponding zero-field-splitting (zfs) D values. The result could be explained by the stability of dinitrene character which is estimated from the resonance energy of the intervening π-system. Our semiempirical molecular orbital calculations supported the experimental correlation between the singlet-triplet energy gap and the zfs D value.
Nitration of a Crude 9,10-Dihydrophenanthrene
Eirin, Ana,Fernandez, Franco,Gomez, Generosa,Lopez, Carmen,Santos, Ana,Rodriguez, Gonzalo
, p. 63 - 66 (2007/10/02)
-