69558-44-7

Upstream product

• 6289-83-4 trans-1,4-diacetoxy-cyclohexane 
• 6995-79-5 cyclohexane-1,4-diol 
• 75-36-5 acetyl chloride 
• 41043-88-3 4-acetoxycyclohexanone 
• 123-31-9 hydroquinone 

Downstream Products

• 6308-92-5 benzoic acid 4-hydroxycyclohexyl ester 
• 5034-21-9 4-(1-oxoethyl)-1-cyclohexanone 
• 1262126-70-4 trans-4-((methoxycarbonyl)oxy)cyclohexyl acetate 
• 23510-95-4 4-benzoyloxycyclohexanone 

Relevant academic research and scientific papers

Synthetic method for cis-1,4-cyclohexanediol

The invention discloses a synthetic method for cis-1,4-cyclohexanediol, belonging to the field of organic chemical synthesis. According to the method, 4-(alkylacyloxy)cyclohexanone is used as a raw material and is only subjected to reduction and hydrolysis so as to conveniently synthesize cis-1,4-cyclohexanediol. The method can guarantee high selectivity of the reactions, and is high in the yieldof cis-1,4-cyclohexanediol and suitable for large-scale production.

Lanthanum(III) isopropoxide catalyzed chemoselective transesterification of dimethyl carbonate and methyl carbamates

A practical transesterification of less reactive dimethyl carbonate and much less reactive methyl carbamates with primary (1°), secondary (2°), and tertiary (3°) alcohols was established with the use of a lanthanum(III) complex, which was prepared in situ from lanthanum (III) isopropoxide (3 mol %) and 2-(2-methoxyethoxy)ethanol (6 mol %). In particular, corresponding carbonates and carbamates obtained were of synthetic utility from the viewpoint of the selective protection and/or deprotection of 1°-, 2°-, and 3°-alcohols.

Facile and highly selective monoacylation of symmetric diols adsorbed on silica gel with acetyl chloride

Monoacetylated alcohols of symmetric 1,n-diols are synthesized quantitatively by refluxing a suspension of the diols adsorbed on silica gel with acetylchloride.