69641-93-6

Usage

Uses

Used in Coordination Chemistry:
DIBUTYL 2,2'-BIPYRIDINE-4,4'-DICARBOXYLATE is used as a ligand for the formation of stable coordination complexes with metal ions. Its role in this field is crucial for the synthesis of metal-organic frameworks and coordination polymers, which are essential in various applications across different industries.
Used in Catalysis:
In the field of catalysis, DIBUTYL 2,2'-BIPYRIDINE-4,4'-DICARBOXYLATE is utilized to enhance the efficiency of chemical reactions. Its ability to form complexes with metal ions allows for the creation of catalytic systems that can improve reaction rates and selectivity.
Used in Sensing:
DIBUTYL 2,2'-BIPYRIDINE-4,4'-DICARBOXYLATE is employed as a component in sensing technologies. Its coordination with metal ions can lead to the development of sensors that are sensitive to specific analytes, which is vital for environmental monitoring, medical diagnostics, and other analytical applications.
Used in Material Science:
In material science, DIBUTYL 2,2'-BIPYRIDINE-4,4'-DICARBOXYLATE is used to develop new materials with unique properties. Its role in the formation of metal-organic frameworks and coordination polymers contributes to the advancement of materials with potential applications in various fields, such as energy storage, gas separation, and molecular sieving.
Used in Luminescent Materials:
DIBUTYL 2,2'-BIPYRIDINE-4,4'-DICARBOXYLATE is used as a component in the development of luminescent materials. Its potential to form complexes with metal ions allows for the creation of materials that exhibit light emission properties, which can be applied in optoelectronics, lighting, and display technologies.
Used in Electronic and Optical Devices:
DIBUTYL 2,2'-BIPYRIDINE-4,4'-DICARBOXYLATE is also utilized in the development of functional materials for electronic and optical devices. Its coordination chemistry properties enable the design of materials with tailored electronic and optical characteristics, which can be integrated into various device applications, such as solar cells, LEDs, and optical sensors.

Upstream product

• 18511-71-2 4,4'-dibromo-2,2'-bipyridine 
• 201230-82-2 carbon monoxide 
• 71-36-3 butan-1-ol 
• 72460-28-7 2,2'-bipyridyl-4,4'-dicarboxylic acid chloride 
• 6813-38-3 2,2'-Bipyridine-4,4'-dicarboxylic acid 
• 1134-35-6 4,4'-dimethyl-2,2'-bipyridines 

Relevant academic research and scientific papers

PT(IV) COMPLEXES CONTAINING 4,4'-DISUBSTITUTED-2,2'-BIPYRIDYL AND THEIR USE IN CANCER THERAPY

Platinum-containing compounds for the treatment of disease, such as, for example, cancer, are provided herein. Specifically, platinum Pt(IV) complexes with a substituted 2,2'-bipyridine ring structure are provided, as are methods for using the complexes.

Evaluation of Tris-Bipyridine Chromium Complexes for Flow Battery Applications: Impact of Bipyridine Ligand Structure on Solubility and Electrochemistry

This report describes the design, synthesis, solubility, and electrochemistry of a series of tris-bipyridine chromium complexes that exhibit up to six reversible redox couples as well as solubilities approaching 1 M in acetonitrile. We have systematically modified both the ligand structure and the oxidation state of these complexes to gain insights into the factors that impact solubility and electrochemistry. The results provide a set of structure-solubility-electrochemistry relationships to guide the future development of electrolytes for nonaqueous flow batteries. In addition, we have identified a promising candidate from the series of chromium complexes for further electrochemical and battery assessment.

Facile synthesis of polypyridine esters: A route to functionalized aldehydes

A wide range of ester-substituted oligopyridines, based on pyridine, 1,8-naphthyridine, 1,10-phenanthroline, 2,2'-bipyridine, and 2,2':6',6-terpyridine units, has been synthesized and fully characterized. The principal reaction involves the palladium(0)-catalyzed carboalkoxylation of the bromo-, chloro- or triflate-substituted pyridine unit with carbon monoxide in the presence of a primary alcohol as nucleophile and a tertiary amine as base. Monofunctionalization of disubstituted compounds is realized by reaction in ethanol under mild conditions (70 °C, 1 atm CO). Stepwise reduction of selected esters with sodium borohydride, followed by Swern oxidation, affords the corresponding carbaldehydes in good yield. Several products are reported for the first time. The synthetic methods reported herein represent a valuable approach to the large-scale preparation of ester-functionalized oligopyridines that can be subsequently transformed to the corresponding alcohols or acids. These procedures also provide a practical methodology to the rational design of ligands bearing different kinds of functionalities.