69688-50-2

Basic information

• Product Name: α-Chloro-α-methylbenzenepropionic acid methyl ester
• Synonyms: α-Chloro-α-methylbenzenepropionic acid methyl ester
• CAS NO: 69688-50-2
• Molecular Formula: C₁₁H₁₃ClO₂
• Molecular Weight: 212.67272
• Mol File: 69688-50-2.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: α-Chloro-α-methylbenzenepropionic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: α-Chloro-α-methylbenzenepropionic acid methyl ester(69688-50-2)
• EPA Substance Registry System: α-Chloro-α-methylbenzenepropionic acid methyl ester(69688-50-2)

Safety Data

• Hazardous Substances Data: 69688-50-2(Hazardous Substances Data)

Upstream product

• 2684-02-8 benzenediazonium 
• 80-62-6 methacrylic acid methyl ester 
• 100-34-5 benzene diazonium chloride 
• 62-53-3 aniline 

Downstream Products

• 123820-51-9 ((Z)-1-Methoxy-2-methyl-3-phenyl-propenyloxy)-trimethyl-silane 
• 65791-96-0 2-Methyl-2-nitro-3-phenyl-propionic acid methyl ester 
• 65791-98-2 2-(1-Methoxycarbonyl-1-methyl-2-phenyl-ethylsulfanyl)-2-methyl-3-phenyl-propionic acid methyl ester 
• 65791-91-5 2-Methyl-3-phenyl-2-thiocyanato-propionic acid methyl ester 

Relevant articles and documents

Reaction of methyl methacrylate with benzenediazonium chloride in the presence of iron(II) chloride

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Direct Conversion of Arylamines to the Halides by Deamination with Thionitrite or Related Compounds and Anhydrous Copper(II) Halides

Reactions of various arylamines with either t-butyl thionitrite, t-butyl thionitrate, or p-toluenesulfonyl nitrite in the presence of anhydrous copper(II) halides under mild conditions gave corresponding aryl halides in good yields.This reaction in the presence of such olefins as acrylonitrile, styrene, and acrylic acid gave the corresponding 2-aryl-1-haloethanes as the main products. t-Butyl thionitrite, t-butyl thionitrate, and p-toluenesulfonyl nitrite were found to be better deaminative reagents than alkyl nitrites or alkyl nitrates due to their weak sulfur-nitrogen bonds.