697-28-9

Basic information

• Product Name: Spiro[4.5]dec-6-ene
• Synonyms: Spiro[4.5]dec-6-ene
• CAS NO: 697-28-9
• Molecular Formula: C₁₀H₁₆
• Molecular Weight: 0
• Mol File: 697-28-9.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Spiro[4.5]dec-6-ene(CAS DataBase Reference)
• NIST Chemistry Reference: Spiro[4.5]dec-6-ene(697-28-9)
• EPA Substance Registry System: Spiro[4.5]dec-6-ene(697-28-9)

Safety Data

• Hazardous Substances Data: 697-28-9(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 56, p. 846, 1991 DOI: 10.1021/jo00002a065

Upstream product

• 10381-61-0 spiro[4.5]decan-6-ol 
• 131195-48-7 cis-7-chlorospiro<4.5>decan-6-ol 
• 104175-51-1 7-chloro-spiro[4.5]decan-6-one 
• 13388-94-8 spiro[4.5]decan-6-one 
• 131195-50-1 cis-7-chlorospiro<4.5>dec-6-yl acetate 
• 131195-50-1 7-chlorospiro<4.5>dec-6-yl acetate 
• 739-08-2 spiro[4.5]decan-6-one p-toluenesulfonylhydrazone 

Downstream Products

• 949530-37-4 3a'-(4-methoxyphenyl)-2',3',3a',4',5',6'-hexahydrospiro[cyclopentan-1,7'-indole] 1'-oxide 
• 949530-35-2 [7-(4-methoxyphenyl)-6-oxo-spiro[4.5]dec-7-yl]acetaldehyde oxime 
• 949530-33-0 [7-(4-methoxyphenyl)-6-oxo-spiro[4.5]dec-7-yl]acetaldehyde 
• 949530-31-8 7-allyl-7-(4-methoxyphenyl)spiro[4.5]decan-6-one 
• 949530-29-4 7-(4-methoxyphenyl)spiro[4.5]decan-6-one 
• 187-24-6 7-oxaspiro[bicyclo[4.1.0]heptane-2,1'-cyclopentane] 
• 14523-53-6 spiro<4.5>dec-6-en-8-one 

Relevant articles and documents

Enantioselective epoxidation of nonconjugated cis-olefins by chiral dioxirane

A variety of nonconjugated cis-olefins has been enantioselectively epoxidized with chiral ketones 2, and up to 92% ee has been obtained. The two prochiral faces of an olefin are likely stereodifferentiated by the relative hydrophobicity of the olefin substituents and/or allylic oxygen functionality.

Electro-reductive cleavage of some tosylhydrazones in the presence of oxygen

The superoxide ion induced fragmentation of tosylhydrazones of p-anisaldehyde (1a) 4-(dimethylamino)benzaldehyde (1b), 2-methylcyclohexanone (1c), 2,2-dimethylcyclohexanone (1d), spirodecan-6-one (1e) and 1-indanone (1f) at mercury catode in DMF affords the olefinic products (2a-f) in good yields.