69718-04-3Relevant academic research and scientific papers
ALKALINE METAL FLUORIDES IN GRAPHITE - NEW CATALYSTS IN ORGANIC SYNTHESIS. I. REACTIONS OF POLYFLUOROAROMATIC COMPOUNDS WITH O- AND N-NUCLEOPHILIC AGENTS
Aksenov, V. V.,Vlasov, V. M.,Danilkin, V. I.,Rodionov, P. P.,Shnitko, G. N.
, p. 57 - 73 (2007/10/02)
The paper reports the use of new catalysts - alkaline metal fluorides in graphite of the general formula C8MF, where M=Li, Na, K, Rb or Cs, in the reactions of polyfluoroaromatic compounds with aromatic OH-acids and piperidine.These compounds are shown to have a high activity in the above processes, exceeding that of similar free fluorides of alkaline metals.
INTERACTION OF PENTAFLUOROPYRIDINE WITH 4-NITROPHENOL AND PENTAFLUOROPHENOL IN THE PRESENCE OF POTASSIUM FLUORIDE AND 18-CROWN-6-ETHER
Aksenov, V. V.,Vlasov, V. M.,Yakobson, G. G.
, p. 439 - 458 (2007/10/02)
The reactions of 4-nitro- and pentafluorophenols with C5F5N, 4-ArOC5F4N and 2,4-(ArO)2C5F3N (Ar = 4-NO2C6H4, C6F5) in the presence of KF and catalytic amounts of 18-crown-6-ether at various temperatures have been investigated.The leaving ability of the C6
