69735-24-6Relevant academic research and scientific papers
Heteronuclear NMR studies of the chromone alkaloids and revision of the structure of some piperidino-chromone alkaloids
Houghton,Osibogun,Woldemariam,Jones
, p. 154 - 157 (1995)
The 13C-NMR spectra of seven chromone alkaloids isolated from Schumanniophyton magnificum have been obtained. Assignment of signals was carried out with the help of heteronuclear coupling experiments and other correlation techniques on the alka
Combined metalation-cross coupling strategies: A synthesis of schumanniophytine by a key biaryl O-carbamate remote anionic fries rearrangement
Macklin, Todd K.,Reed, Mark A.,Snieckus, Victor
supporting information; scheme or table, p. 1507 - 1509 (2009/04/11)
A short synthesis of the alkaloid schumanniophytine (1) starting from simple building blocks and involving directed ortho metalation (DoM), Suzuki-Miyaura cross coupling, and a key ortho-silicon-induced O-carbamate remote anionic Fries rearrangement (3) is described. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
