697741-23-4

Upstream product

• 121573-17-9 (3aR,7aS)-2,2-dimethyltetrahydrobenzo[d][1,3]dioxol-5(6H)-one 
• 74293-60-0 (3aR,7R,7aS)-7-hydroxy-2,2-dimethyltetrahydrobenzo[d][1,3]dioxol-5(6H)-one 
• 121651-99-8 (4S,5R)-4,5-O-isopropylidenedioxycyclohex-2-en-1-one 
• 32384-42-2 (1S,3R,4S,5R)-3,4-O-isopropylidene-1,5-quinic lactone 
• 119478-74-9 (S)-4-((tert-butyldimethylsilyl)oxy)cyclohex-2-enone 
• 697741-19-8 (8S,10R)-8-(tert-butyldimethylsilyloxy)-10-phenylthio-1,4-dioxaspiro[4.5]dec-6-ene 
• 697741-20-1 (4S)-4-(tert-butyldimethylsilyloxy)-10-phenylthiocyclohex-2-enone 
• 697741-18-7 (8S,10R)-10-phenylthio-1,4-dioxaspiro[4.5]dec-6-en-8-ol 

Downstream Products

• 132617-15-3 (1R,4S)-4-hydroxycyclohex-2-en-1-yl acetate 
• 94597-61-2 (S)-(-)-4-isopropenyl-2-cyclohexen-1-one 

Relevant academic research and scientific papers

Further study on synthesis of the cyclobakuchiols

Abstract Two results are described. First, quinic acid was transformed into the monoacetate of 2-cyclohexene-1,4-diol. The Ni-catalyzed allylic substitution of the monoacetate with CH2C(Me)MgBr/ZnCl2/TMEDA followed by oxidation of th

An efficient protocol for the enantioselective preparation of a key polyfunctionalized cyclohexane. New access to (R)- and (S)-4-hydroxy-2- cyclohexenone and (R)- and (S)-trans-cyclohex-2-ene-1,4-diol

(Chemical Equation Presented) Starting from very accessible raw materials such as p-methoxyphenol, ethylene glycol, and thiophenol, a protocol has been developed to prepare multigram quantities of the polyfunctionalized cyclohexane (±)-7. A highly efficie

An efficient approach to either enantiomer of trans-cyclohex-2-ene-1,4-diol

(1S,4S)-Cyclohex-2-ene-1,4-diol has been synthesised starting from a chiral p-benzoquinone equivalent. The sequence can be equally applied to the preparation of the (1R,4R)-enantiomer of the target diol.