697741-23-4Relevant articles and documents
Further study on synthesis of the cyclobakuchiols
Kawashima, Hidehisa,Sakai, Masahiro,Kaneko, Yuki,Kobayashi, Yuichi
, p. 2387 - 2392 (2015/03/30)
Abstract Two results are described. First, quinic acid was transformed into the monoacetate of 2-cyclohexene-1,4-diol. The Ni-catalyzed allylic substitution of the monoacetate with CH2C(Me)MgBr/ZnCl2/TMEDA followed by oxidation of th
An efficient approach to either enantiomer of trans-cyclohex-2-ene-1,4-diol
Alibes, Ramon,De March, Pedro,Figueredo, Marta,Font, Josep,Marjanet, Georgina
, p. 1151 - 1155 (2007/10/03)
(1S,4S)-Cyclohex-2-ene-1,4-diol has been synthesised starting from a chiral p-benzoquinone equivalent. The sequence can be equally applied to the preparation of the (1R,4R)-enantiomer of the target diol.