94597-61-2

Upstream product

• 145747-47-3 ((S)-4-Isopropenyl-cyclohex-1-enyloxy)-trimethyl-silane 
• 190718-78-6 ((4S)-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-1-yl)methanol 
• 119478-74-9 (S)-4-((tert-butyldimethylsilyl)oxy)cyclohex-2-enone 
• 942514-50-3 (1R,4S)-4-((tert-butyldimethylsilyl)oxy)cyclohex-2-enol 
• 697741-23-4 (1S,4S)-4-((tert-butyldimethylsilyl)oxy)cyclohex-2-enol 
• 132617-15-3 (1R,4S)-4-hydroxycyclohex-2-en-1-yl acetate 
• 74293-60-0 (3aR,7R,7aS)-7-hydroxy-2,2-dimethyltetrahydrobenzo[d][1,3]dioxol-5(6H)-one 
• 121573-17-9 (3aR,7aS)-2,2-dimethyltetrahydrobenzo[d][1,3]dioxol-5(6H)-one 
• 94597-65-6 (S)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-4-isopropenyl-2-phenylselanyl-cyclohexanol 
• 38651-65-9 (1R,5S)-(+)-nopinone 
• 935745-93-0 (S)-1-Hydroxymethyl-4-isopropenyl-2-phenylselanyl-cyclohexanol 
• 132042-13-8 (S)-(-)-1-Acetoxy-4-(1-acetoxy-1-methylethyl)-1-cyclohexene 
• 132077-84-0 (S)-(-)-1-Acetoxy-4-isopropenyl-1-cyclohexene 

Downstream Products

• 94597-68-9 (2R,3R,4S)-2-((E)-(R)-1-Hydroxy-but-2-enyl)-4-isopropenyl-3-vinyl-cyclohexanone 
• 94668-63-0 (2R,3R,4S)-2-((E)-(S)-1-Hydroxy-but-2-enyl)-4-isopropenyl-3-vinyl-cyclohexanone 
• 94597-82-7 N-((4'aS,5'R,8'aS)-5'-Methyl-8'-phenylselanyl-octahydro-spiro[[1,3]dioxolane-2,2'-naphthalen]-5'-yl)-acetamide 
• 94597-79-2 N-((1R,4aS,8aS)-1-Methyl-6-oxo-decahydro-naphthalen-1-yl)-benzamide 
• 94597-78-1 N-((1S,4aS,8aS)-1-Methyl-6-oxo-decahydro-naphthalen-1-yl)-benzamide 

Relevant academic research and scientific papers

Further study on synthesis of the cyclobakuchiols

Abstract Two results are described. First, quinic acid was transformed into the monoacetate of 2-cyclohexene-1,4-diol. The Ni-catalyzed allylic substitution of the monoacetate with CH2C(Me)MgBr/ZnCl2/TMEDA followed by oxidation of th

Efficient and convenient syntheses of (R)-(-)-cryptone and (S)-(-)-isopropenyl-2-cyclohexen-1-one

Starting with (+)-nopinone (3); (R)-(-)-cryptone (1) and (S)(-)-4-isopropenyl-2-cyclohexen-1-one (2) were synthesized in five steps and 42% overall yield, and four steps and 49% overall yield, respectively.

Synthetic Approach to the Amphilectane Diterpenes: The Use of Nitriles as Terminators of Carbocation-Olefin Cyclizations

A biomimetic approach to the synthesis of tricyclic terpenoid isonitriles from marine sponges is described which involves carbocation-olefin cyclization of polyolefinic precursors terminated by the stereoselective formation of a carbon-nitrogen bond.The k