698378-88-0Relevant articles and documents
On the mechanism of stereoselection in direct Mannich reaction catalyzed by BINOL-derived phosphoric acids
Gridnev, Ilya D.,Kouchi, Mitsuhiro,Sorimachi, Keiichi,Terada, Masahiro
, p. 497 - 500 (2007)
Associates between the chiral phosphoric acids and Boc-protected imine were characterized computationally and by NMR; the primary importance of the bulky protecting group in imine for the high enantioselectivity in the direct Mannich reaction is rationali
Decrypting Transition States by Light: Photoisomerization as a Mechanistic Tool in Br?nsted Acid Catalysis
Renzi, Polyssena,Hioe, Johnny,Gschwind, Ruth M.
supporting information, p. 6752 - 6760 (2017/05/29)
Despite the wide applicability of enantioselective Br?nsted acid catalysis, experimental insight into transition states is very rare, and most of the mechanistic knowledge is gained by theoretical calculations. Here, we present an alternative approach (de
BIS-PHOSPHATE COMPOUND AND ASYMMETRIC REACTION USING THE SAME
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Page/Page column 25-26, (2013/02/28)
A novel bis-phosphate compound is provided which can be applied to a wide range of reactive substrates and reactions as an asymmetric reaction catalyst and can realize an asymmetric reaction affording a high yield and a high enantiomeric excess. The bis-p
