69847-28-5

Upstream product

• 69847-29-6 N-[2,4,6-tri(tert-butyl)phenyl]-formamide 

Downstream Products

• 103602-06-8 Pt₃(2,4,6-tri-t-butylphenyl isocyanide)6 
• 127161-80-2 {Pd₃(2,4,6)-(tri-t-butylphenyl isocyanide)6} 
• 127253-79-6 PtCl₂-bis(2,4,6-tri-t-butylphenyl isocyanide) 
• 127615-03-6 {Re(CN(C₄H₉)3C₆H₂)5}Br 
• 127615-02-5 {Re(CN(C₄H₉)3C₆H₂)5}Cl 
• 128324-91-4 {Re(CN(C₄H₉)3C₆H₂)6}⁽¹⁺⁾*PF₆^(1-)={Re(CN(C₄H₉)3C₆H₂)6}PF₆ 
• 391689-21-7 2,4,6-tris[bis(trimethylsilyl)methyl]phenylSiH₂BH(mesityl)CN(2,4,6-tri-tert-butylphenyl) 
• 1234675-09-2 2,4,6-tri-tert-butyl-N-(9H-fluoren-9-ylidene)aniline 
• 1392826-45-7 N,4-diphenyl-2-(2,4,6-tri-tert-butylphenylimino)butanamide 
• 98161-15-0 hexakis(2,4-tri-t-butyl-phenyl isocyanide)molybdenum 
• 104911-62-8 Mo(C₃H₅)Cl(CO)2(CNC₆H₂(C(CH₃)3)3)2 
• 104911-70-8 Mo(P(C₃H₇)3)2(CO)2(CNC₆H₂(C(CH₃)3)3)2 

Relevant academic research and scientific papers

Reversible intramolecular coupling of the terminal borylene and a carbonyl ligand of [Cp(CO)2Mn=B-tBu]

Cyclic complex 2 with bridging carbonyl ligands was synthesized from a facile and reversible intermolecular carbonyl-borylene ligand coupling reaction at room temperature. Complex 2 exhibits an unprecedented coordination mode for boron-metal complexes, which is also reflected in its remarkable 11B NMR chemical shift of -57.2 ppm. Findings from spectroscopic, X-ray, and computational studies are presented, along with a proposed mechanism. Copyright

Fragmentation of an n-substituted one-coordinate phosphorus (Phosphaalkyne): Plausible generation of monovalent phosphorus species

A new one-step synthesis of a stable nitrogen-substituted phosphaalkyne (5) was developed, by the condensation of CsF (2), tris(trimethylsilyl)phosphine (3), and supermesityl isocyanate (4). Compound 5 has the longest terminal CP bond (1.617 A) of any phosphaalkyne. Due to electron delocalization on the terminal phosphorus atom in 5, fragmentation to a monovalent phosphorus species (CsP (9)) and supermesityl isonitrile (8) is plausible. Isonitrile (8) was isolated in pure form. CsP (9) was trapped as a tricesium pentaphosphorus compound (10) and also as cesium [1,2,4]triphospholide (13).