98161-17-2

Basic information

• Product Name: hexakis(2,4-tri-t-butyl-phenyl isocyanide)tungsten
• Synonyms: hexakis(2,4-tri-t-butyl-phenyl isocyanide)tungsten
• CAS NO: 98161-17-2
• Molecular Weight: 1812.53
• Mol File: 98161-17-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: hexakis(2,4-tri-t-butyl-phenyl isocyanide)tungsten(CAS DataBase Reference)
• NIST Chemistry Reference: hexakis(2,4-tri-t-butyl-phenyl isocyanide)tungsten(98161-17-2)
• EPA Substance Registry System: hexakis(2,4-tri-t-butyl-phenyl isocyanide)tungsten(98161-17-2)

Safety Data

• Hazardous Substances Data: 98161-17-2(Hazardous Substances Data)

Upstream product

• 69847-28-5 2,4,6‐tri‐tert‐butylphenylisocyanide 
• 13283-01-7 tungsten(VI) chloride 

Relevant articles and documents

STUDIES ON THE INTERACTION OF ISOCYANIDES WITH TRANSITION METAL COMPLEXES. XXVII. PREPARATION OF ZEROVALENT ISOCYANIDE COMPLEXES OF CHROMIUM, MOLYBDENUM AND TUNGSTEN. THE CRYSTAL STRUCTURE OF HEXAKIS(2,6-XYLYLISOCYANIDE)MOLYBDENUM CONTAINING BENZENE AS A SOLVATED MOLECULE

Hexakis(isocyanide)metals, M(RNC)6 (M=Cr, Mo, W; R=2,6-Me2C6H4, 2,4,6-Me3C6H2, 2,4-t-Bu2-6-MeC6H2, 2,4,6,-t-Bu3C6H2 and t-Bu), were prepared by the reduction of a halide of chromium(III), molybdenum(IV), molybdenum(V) or tungsten(VI) with sodium amalgam in the presence of an isocyanide.An X-ray crystallographic study of Mo(2,6-Me2C2H3NC)6*C6H6 revealed that the molybdenum atom is approximately octahedrally coordinated by six isocyanide ligands.