69853-85-6Relevant academic research and scientific papers
Heterolytic Oxygen-Oxygen Bond Formation via gem-Dialkylperoxonium Ions
Best, Stephen P.,Bloodworth, A. J.,Spencer, Michael D.
, p. 416 - 418 (1990)
Different extents of decomposition for the cis and trans isomers of 4,5-epoxycyclo-octyl hydroperoxide coupled with the formation of oxygen (identified by Raman spectroscopy) and bicyclic ethers suggest a mechanism involving the heterolytic formation of protonated alkyl hydrotrioxides by nucleophilic attack of hydroperoxide on gem-dialkylperoxonium ions.
