Journal of the Chemical Society. Chemical communications p. 416 - 418 (1990)
Update date:2022-08-04
Topics:
Best, Stephen P.
Bloodworth, A. J.
Spencer, Michael D.
Different extents of decomposition for the cis and trans isomers of 4,5-epoxycyclo-octyl hydroperoxide coupled with the formation of oxygen (identified by Raman spectroscopy) and bicyclic ethers suggest a mechanism involving the heterolytic formation of protonated alkyl hydrotrioxides by nucleophilic attack of hydroperoxide on gem-dialkylperoxonium ions.
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Doi:10.1021/acs.orglett.9b03505
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