69894-07-1

Basic information

• Product Name: 2-(phenyl)amino-4-(phenyl)imino-2-pentene
• CAS NO: 69894-07-1
• Molecular Weight: 250.343
• Mol File: 69894-07-1.mol

Chemical Properties

• CAS DataBase Reference: 2-(phenyl)amino-4-(phenyl)imino-2-pentene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(phenyl)amino-4-(phenyl)imino-2-pentene(69894-07-1)
• EPA Substance Registry System: 2-(phenyl)amino-4-(phenyl)imino-2-pentene(69894-07-1)

Safety Data

• Hazardous Substances Data: 69894-07-1(Hazardous Substances Data)

Upstream product

• 16195-91-8 N-cyclohexyl-4-amino-3-penten-2-one 
• 1510707-07-9 C₁₀H₁₇NO 
• 59487-13-7 N-tert-butyl-4-amino-3-penten-2-one 
• 62-53-3 aniline 
• 59487-11-5 N-isopropyl-4-amino-3-penten-2-one 
• 7294-89-5 4-(phenylamino)pent-3-en-2-one 
• 108-91-8 cyclohexylamine 
• 123-54-6 acetylacetone 
• 24345-25-3 3-methoxy-1-methyl-but-2-enylideneamine; methyl sulfate 
• 49784-51-2 4-chloropent-3-en-2-one 

Downstream Products

• 1510680-78-0 C₁₅H₂₆N₂ 

Relevant articles and documents

General and highly active catalyst for mono and double Hiyama coupling reactions of unreactive aryl chlorides in water

A new β-diketiminatophosphane Pd catalyst was found to be highly effective in the mono and double Hiyama coupling reactions of unactivated aryl chlorides in water.

Werner-Type Complexes of Uranium(III) and (IV)

Transmetalation of the β-diketiminate salt [M][MenacnacPh] (M+ = Na or K; MenacnacPh- = {PhNC(CH3)}2CH-) with UI3(THF)4 resulted in the formation

Rational Design of an Iron-Based Catalyst for Suzuki–Miyaura Cross-Couplings Involving Heteroaromatic Boronic Esters and Tertiary Alkyl Electrophiles

Suzuki–Miyaura cross-coupling reactions between a variety of alkyl halides and unactivated aryl boronic esters using a rationally designed iron-based catalyst supported by β-diketiminate ligands are described. High catalyst activity resulted in a broad substrate scope that included tertiary alkyl halides and heteroaromatic boronic esters. Mechanistic experiments revealed that the iron-based catalyst benefited from the propensity for β-diketiminate ligands to support low-coordinate and highly reducing iron amide intermediates, which are very efficient for effecting the transmetalation step required for the Suzuki–Miyaura cross-coupling reaction.

Synthesis of Lewis Acidic, Aromatic Aminotroponiminate Zinc Complexes for the Ring-Opening Polymerization of Cyclic Esters

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The steric influence of β-diketiminato ligands on the coordination chemistry of lead(II)

Three new β-diketiminatolead(II) chlorides have been synthesised, including [(BDIDMP)PbCl], [(BDIIPP)PbCl] and [(BDIPh)PbCl] (BDIDMP = [N{(2,6-Me2C6H3)C(Me)}2CH], BDI

Friedel-crafts alkylation of toluene as a parallel reaction in propylene dimerization catalyzed by nickel β-diimine complex/EASC in homogeneous phase

Propylene oligomerization was performed using dibromo-bis(N,N'-diphenylpentane-2,4- diimine)nickel(II) complex as catalytic precursor combined with ethyl aluminum sesquichloride (Al2Et3Cl3, EASC) as co-catalyst. At 10 °C, using toluene as solvent, high turnover frequencies (up to 57,000 h-1) with high selectivities to C6 products (up to > 99percent) and moderate linear C6 selectivity (up to 29percent) were obtained. Under our reaction conditions propylene reacted with toluene through Friedel-Crafts reaction. Increasing the concentration of catalyst precursor keeping the nickel complex/co-catalyst ratio constant increased the selectivity of the oligomerization products vs. Friedel-Craft products.

Novel syntheses of symmetric Alkyl-substituted β-Diketimines with Dimethylsulfate assisted by microwave

We present an efficient and new preparative method for the symmetric β-diketimines assisted by microwave. A series of N,N'-symmetrically alkyl substituted β-diketimines have been synthesized from the reaction of Oacylation with dimethylsulfate. Higher rep

A highly active and general catalyst for the stille coupling reaction of unreactive aryl, heteroaryl, and vinyl chlorides under mild conditions

A β-diketiminatophosphane-palladium complex was found to act as an efficient and general catalyst in the Stille coupling reaction of various aryl and heteroaryl chlorides with organostannanes. The results show that this catalytic system allows for the use of less reactive substrates such as deactivated or sterically hindered aryl chlorides. A catalyst loading of 0.5 mol% was sufficient to achieve excellent performance under relatively mild reaction conditions. Furthermore, the scope of catalyst was extended to the coupling of vinyl chlorides. Copyright

An extremely active and general catalyst for Suzuki coupling reaction of unreactive aryl chlorides

β-Diketiminatophosphane Pd complex 2a acted as a powerful catalyst which allows easy access to the Suzuki coupling reaction of less reactive aryl chlorides under mild conditions. A wide range of sterically hindered and deactivated aryl chlorides could be efficiently coupled at a low catalyst loading of 0.1 mol %. Furthermore, this catalytic system also proved to be highly effective in one-pot multiple couplings.

Highly active palladium catalyst for the sonogashira coupling reaction of unreactive aryl chlorides

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