698976-14-6

Basic information

• Product Name: (1S,5S,7aS)-5-[(1S)-1-[[(1,1-dimetylethyl)dimethylsilyl]oxy]-5-[(4-methoxyphenyl)methoxy]pentyl]-1-[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]propyl]-5,7a-dihydro-1H,3H-pyrrolo[1,2-c]oxazol-3-one
• Synonyms: (1S,5S,7aS)-5-[(1S)-1-[[(1,1-dimetylethyl)dimethylsilyl]oxy]-5-[(4-methoxyphenyl)methoxy]pentyl]-1-[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]propyl]-5,7a-dihydro-1H,3H-pyrrolo[1,2-c]oxazol-3-one
• CAS NO: 698976-14-6
• Molecular Weight: 634.017
• Mol File: 698976-14-6.mol

Chemical Properties

• CAS DataBase Reference: (1S,5S,7aS)-5-[(1S)-1-[[(1,1-dimetylethyl)dimethylsilyl]oxy]-5-[(4-methoxyphenyl)methoxy]pentyl]-1-[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]propyl]-5,7a-dihydro-1H,3H-pyrrolo[1,2-c]oxazol-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,5S,7aS)-5-[(1S)-1-[[(1,1-dimetylethyl)dimethylsilyl]oxy]-5-[(4-methoxyphenyl)methoxy]pentyl]-1-[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]propyl]-5,7a-dihydro-1H,3H-pyrrolo[1,2-c]oxazol-3-one(698976-14-6)
• EPA Substance Registry System: (1S,5S,7aS)-5-[(1S)-1-[[(1,1-dimetylethyl)dimethylsilyl]oxy]-5-[(4-methoxyphenyl)methoxy]pentyl]-1-[3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]propyl]-5,7a-dihydro-1H,3H-pyrrolo[1,2-c]oxazol-3-one(698976-14-6)

Safety Data

• Hazardous Substances Data: 698976-14-6(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 698976-09-9 3-{1-[1-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-pentyl]-allyl}-5-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-vinyl-oxazolidin-2-one 

Downstream Products

• 698976-62-4 (S)-1-{(2S,5S)-5-[(S)-1-Hydroxy-5-(4-methoxy-benzyloxy)-pentyl]-pyrrolidin-2-yl}-butane-1,4-diol 
• 698976-59-9 (1S,5S,7aS)-5-[(S)-1-Hydroxy-5-(4-methoxy-benzyloxy)-pentyl]-1-(3-hydroxy-propyl)-tetrahydro-pyrrolo[1,2-c]oxazol-3-one 
• 698976-40-8 (3S,9S,9aS)-9-[[(1,1-dimetylethyl)diphenylsilyl]oxy]-3-[(1S)-1,4-bis[[(1,1-dimethylethyl)diphenylsilyl]oxy]-butyl]-1H-pyrrolo[1,2-a]azepine 
• 698976-33-9 (S)-5-{(2S,5S)-5-[(S)-1,4-Bis-(tert-butyl-diphenyl-silanyloxy)-butyl]-pyrrolidin-2-yl}-5-(tert-butyl-diphenyl-silanyloxy)-pentan-1-ol 
• 698976-27-1 (2S,5S)-2-[(S)-1,4-Bis-(tert-butyl-diphenyl-silanyloxy)-butyl]-5-[(S)-1-(tert-butyl-diphenyl-silanyloxy)-5-(4-methoxy-benzyloxy)-pentyl]-pyrrolidine 
• 698976-20-4 5-[1-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-pentyl]-1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-tetrahydro-pyrrolo[1,2-c]oxazol-3-one 

Relevant articles and documents

Studies on the synthesis of croomine: Synthesis of the tricyclic B,C,D-ring core structure

A convergent and asymmetric synthesis of the tricyclic B,C,D-ring core structure of croomine has been achieved, using aminolysis reactions of chiral vinyl epoxides and the RCM reaction.