698989-74-1Relevant academic research and scientific papers
Chemistry of polyhalogenated nitrobutadienes, part 5: Synthesis and reactions of dichloromethyl nitrovinylidene ketones of heterocycles
Zapol'skii, Viktor A.,Namyslo, Jan C.,Gjikaj, Mimoza,Kaufmann, Dieter E.
, p. 1507 - 1512 (2007)
An easy access to dichloromethyl nitrovinylidene ketones of five-membered heterocycles is presented starting from nitroperchlorobutadiene. These complex ketones are valuable starting materials for novel product structures in versatile reactions such as selective reductions, substitutions to give α-nitroacryl cyanides, fragmentations by means of an alkoxide, as well as ring-cleavage/ring-closure steps by the action of hydrazine. Some of the products show biological activity in crop protection. Georg Thieme Verlag Stuttgart.
