699023-60-4Relevant articles and documents
Palladium-catalyzed [3,3] sigmatropic rearrangement of (allyloxy) iminodiazaphospholidines: Allylic transposition of C-O and C-N functionality
Lee, Ernest E.,Batey, Robert A.
, p. 1865 - 1868 (2004)
A PV=N to PV=O interconversion is the thermodynamic driving force for the title reaction. Iminodiazaphospholidines 1 give phosphoramides 2, which are subsequently hydrolyzed under mild acidic conditions to yield primary or tosylamines 3. R = alkyl, phenyl; Ts = p-toluenesulfonyl.