69945-43-3Relevant academic research and scientific papers
A Ring Opening Reaction of Hydroperoxides of Cyclic Ethers
Ockels, W.,Stein, J.,Budzikiewicz, H.
, p. 90 - 94 (2007/10/02)
2-Hydroperoxides of cyclic esters react with pyridine-2,6-di(monothiocarboxylic acid) in form of its iron complex by attack of the thiocarboxylate anion at C-3, opening of the ether ring and formation of a thioester carrying a acyloxy group in the alcohol portion.A typical example is the formation of pyridine-2,6-di(monothiocarboxylic acid)-di-S-(3-formoxypropyl)ester from tetrahydrofuran-2-hydroperoxide. - Keywords: Ring Opening Reaction, Hydroperoxides, Cyclic Ethers
Further Pyridine Derivatives Isolated from the Culture Medium of Pseudomonas putida - Genuine Metabolites or Artefacts?
Budzikiewicz, H.,Hildebrand, U.,Ockels, W.,Reiche, M.,Taraz, K.
, p. 516 - 520 (2007/10/02)
From the culture medium of Pseudomonas putida after treatment with CH2N2 besides the expected Pyridine-2,6-di(monothiocarboxylic acid)-di-S-methyl ester a series of pyridine derivatives could be isolated which could be shown to be artefacts formed from pyridine-2,6-di(monothiocarboxylic acid). - Keywords: Pyridine Derivatives, Bacterical Metabolites, Pseudomonas putida, Thiocarboxylic Acid Chemistry
