69945-43-3Relevant articles and documents
A Ring Opening Reaction of Hydroperoxides of Cyclic Ethers
Ockels, W.,Stein, J.,Budzikiewicz, H.
, p. 90 - 94 (2007/10/02)
2-Hydroperoxides of cyclic esters react with pyridine-2,6-di(monothiocarboxylic acid) in form of its iron complex by attack of the thiocarboxylate anion at C-3, opening of the ether ring and formation of a thioester carrying a acyloxy group in the alcohol portion.A typical example is the formation of pyridine-2,6-di(monothiocarboxylic acid)-di-S-(3-formoxypropyl)ester from tetrahydrofuran-2-hydroperoxide. - Keywords: Ring Opening Reaction, Hydroperoxides, Cyclic Ethers