6997-96-2Relevant articles and documents
Reductive N-alkylation of aromatic amines and nitro compounds with nitriles using polymethylhydrosiloxane
Reddy, Ch. Raji,Vijeender,Bhusan, P. Bibhuti,Madhavi, P. Phani,Chandrasekhar
, p. 2765 - 2768 (2007)
The potential utility of polymethylhydrosiloxane (PMHS) as a reducing agent for reductive N-alkylation of aromatic amines and nitro compounds using nitriles as an alkylating agent and Pd(OH)2/C as a catalyst is described. The application of this method for the synthesis of several heterocyclic compounds is also reported.
Lithium tetrafluoroborate catalyzed highly efficient inter- and intramolecular aza-Michael addition with aromatic amines
Lad,Kulkarni,Desai,Wadgaonkar
experimental part, p. 1059 - 1064 (2012/03/11)
Lithium tetrafluoroborate has been demonstrated for the first time to be an efficient catalyst in intermolecular aza-Michael addition aromatic amines to electron deficient alkenes. Suitability of the same catalyst in intramolecular aza-Michael addition leading 2-aryl-2,3-dihydroquinolin-4(1H) ones has also been described.