700377-46-4Relevant academic research and scientific papers
Enantioface-selective coordination of prochiral 1,3-dienes to planar-chiral cyclopentadienyl-ruthenium complexes
Matsushima, Yuji,Onitsuka, Kiyotaka,Takahashi, Shigetoshi
, p. 2439 - 2446 (2008/10/09)
The treatment of planar-chiral (η5:η1- cyclopentadienylphosphine)bis(acetonitrile)rutheniumcomplexes 1 with prochiral dienes led to the ligand-exchange reaction that gave (η5: η1-cyclopentadienylphosphine)(ηsup
Enantioface-selective complexation of prochiral dienes on planar-chiral cyclopentadienylruthenium complexes bearing an anchor phosphine ligand
Matsushima, Yuji,Onitsuka, Kiyotaka,Takahashi, Shigetoshi
, p. 760 - 761 (2007/10/03)
Planar-chiral cyclopentadienylruthenium complex 1 [{η5:η1-C5H2-2-Me-4-Ph-1-CO2 CH2CH2PPh2}Ru(CH3CN)2][PF 6] bearing an anchor phosphine ligand exhibits a high enantioface selectivity in the reaction with prochiral dienes 2 to give planarchiral η4-diene complex 3.
