700380-77-4Relevant articles and documents
4-Chloro-5-methyl-3-diphenylphosphino-1-phenyl-1,2,3,6- tetrahydrophosphinine as a bidentate P-ligand in a cis chelate Pt(II) complex
Keglevich, Gy?rgy,Sipos, Melinda,Szieberth, Dénes,Petocz, Gy?rgy,Kollár, László
, p. 3158 - 3162 (2004)
Double deoxygenation of a 3-phosphinoxido-1,2,3,6-tetrahydrophosphine oxide (2) led to bisphosphine 3-2 with an inverted ring P atom. The reaction of bidentate P-ligand 3-2 with dichlorodibenzonitrilo platinum(II) yielded the mixture of a novel cis chelat
Enzymatic synthesis of optically active α-chloro-δ-hydroxy- β-ketoalkanephosphonates and reactions thereof
Xu, Chengfu,Yuan, Chengye
, p. 3883 - 3892 (2007/10/03)
A novel and enzymatic approach to α-chloro-δ-hydroxy-β- ketoalkanephosphonates was developed via enantioselective CALB-catalyzed acetylation and CRL-catalyzed hydrolysis. The resultant optically active compounds provide, via Horner-Wadsworth-Emmons (HWE)