70042-49-8Relevant articles and documents
A Novel Route to Geminal Dibromocyclobutanes: Syntheses of 2-Substituted Cyclobutanone Acetals and Their Reaction with Boron Tribromide
Nordvik, Tore,Brinker, Udo H.
, p. 9394 - 9399 (2007/10/03)
Nine 2-substituted cyclobutanone acetals, in addition to the parent cyclobutanone acetal, were synthesized from their corresponding cyclobutanones and subsequently treated with boron tribromide. The substituents were either alkyl chains or a phenyl and a
FLUORIDE-CATALYZED CONDENSATION OF 1-PHENYLSULFINYL-1-(TRIMETHYLSILYL)CYCLOPROPANE WITH CARBONYL COMPOUNDS
Pohmakotr, Manat,Sithikanchanakul, Srisamorn
, p. 477 - 484 (2007/10/02)
1-Phenylsulfinyl-1-(trimethylsilyl)cyclopropane reacts with aldehydes in the presence of Bu4NF to give 1-phenylsulfinyl-1-(α-hydroxyalkyl)cyclopropanes.
A New and Convenient Synthetic Method for Cyclopropyl Phenyl Sulfides
Tanaka, Kazuhiko,Uneme, Hideki,Matsui, Shuichi,Kaji, Aritsune
, p. 2965 - 2972 (2007/10/02)
The reactions of a variety of 1,3-bis(phenylthio)propanes with butyllithium have been shown to produce cyclopropyl phenyl sulfides in good to high yields.A new and convenient in situ preparation of 1-lithiocyclopropyl phenyl sulfide can be readily carried out by treating 1,3-bis(phenylthio)propane with 2 equiv. of butyllithium at 0 degC in THF.The reaction with electrophiles proceeds in good yield.O-Aryl and O-alkyl S-cyclopropyl dithiocarbonates also can be prepared in good yields. 1,2-Bis(phenylthio)ethane was converted to phenyl vinyl sulfide on treatment with butyllithium, while 1,4-bis(phenylthio)butane was recovered unchanged by a similar treatment.