91454-72-7Relevant academic research and scientific papers
INTRAMOLECULAR CYCLIZATION OF o-SILYLBENZYL ALCOHOLS WITH ELIMINATION OF HYDROCARBON VIA HYPERVALENT SILICON INTERMEDIATES: EFFECT OF STRUCTURE ON THE SELECTIVITY FOR ELIMINATION
Yamamoto, Yoshuke,Takeda, Yasuhiro,Akiba, Kin-ya
, p. 725 - 728 (2007/10/02)
o-Silylbenzyl alcohols (1a-1e) cyclized with elimination of hydrocarbon to give cyclic silanes (2) in quantitative yield.The cyclization took place only in aprotic polar solvents such as acetonitrile, indicating that the intermediate of the cyclization wa
The Crystal and Molecular Structure of Tris(substituted amino) Sulfonium Ions
Farnham, William B.,Dixon, David A.,Middleton, William J.,Calabrese, Jodeph C.,Harlow, Richard L.,et al.
, p. 476 - 483 (2007/10/02)
The synthesis and crystal structures determined by X-ray diffraction techniques for a number of salts of the tris(dimethylamino)sulfonium cation (methyl-TAS) are reported.The strucutres of the methyl-TAS cation are all wery similar, and the cation possess
