70133-99-2Relevant academic research and scientific papers
1,7-Dithioxo systems. Reaction of bis(5,5-dimethyl-3-thioxo-cyclohex-1-en- 1-yl) sulfide with amines
Timokhina,Sokol'nikova,Kanitskaya,Yashchenko,Voronkov
experimental part, p. 532 - 535 (2009/04/11)
Reactions of amines (N,N-dimethylethane-1,2-diamine, benzylamine, aniline) with bis(5,5-dimethyl-3-thioxocyclohex-1-en-1-yl) sulfide result in cleavage of the sulfide bond and formation of the corresponding 3-amino-5,5- dimethylcyclohex-2-ene-1-thiones. A
The Reaction of Enaminothiones with Methyleniminium Salts
Moehrle, Hans,Bangert, Reinhard
, p. 1187 - 1190 (2007/10/02)
The N-primary and N-secondary enaminothiones derived from dimedone yield with methyleniminium salts the C-Mannich bases only.
ALKYLIERUNGSREAKTIONEN AN THIOAMIDEN, VII. ALKYLIERUNG VON VINYLOGEN THIOAMIDEN UND STEREOCHEMIE DER ALKYLIERUNGSPRODUKTE
Walter, Wolfgang,Saha, Chantu Ranjan
, p. 367 - 385 (2007/10/02)
On reacting the cyclic enaminothiones 1 with alkyl halides and pulverized sodiumhydroxide in acetone, the hitherto difficultly accessible thioenimines 8 are obtained in fair yield.They show Z-E isomerism at the substituted imino group.The isomers were ass
α,β-UNSATURATED THIO COMPOUNDS. XIII.* HYDROTHIOLYSIS OF β-HETERO-SUBSTITUTED α,β-UNSATURATED IMMONIUM SALTS AT THE C=N(+) BOND - A GENERAL APPROACH TO THE SYNTHESIS OF FUNCTIONALLY SUBSTITUTED THIOKETONES
Usov, V. A.,Timokhina, L. V.,Zhagun, V. A.,Sidorkin, V. F.,Voronkov, M. G.
, p. 1623 - 1628 (2007/10/02)
The hydrothiolysis of immonium salts containing the Y-C=C-C=N(+) group takes place at the C=N(+) bond and not at the C-Y bond.This is consistent with the results from quantum-chemical calculations.On this basis a general approach was formulated to the synthesis of new types of organic sulfur compounds, i.e. β-alkoxy-, β-alkylthio-, and β-halogen-substituted α,β-unsaturated thioketones of the Y-C=C-C=S (Y=RO, RS, Hlg) type.
