80371-87-5

Basic information

• Product Name: N-(3-methoxy-5,5-dimethyl-2-cyclohexen-1-ylidene)pyrrolidinium iodide
• Synonyms: N-(3-methoxy-5,5-dimethyl-2-cyclohexen-1-ylidene)pyrrolidinium iodide
• CAS NO: 80371-87-5
• Molecular Weight: 335.228
• Mol File: 80371-87-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(3-methoxy-5,5-dimethyl-2-cyclohexen-1-ylidene)pyrrolidinium iodide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3-methoxy-5,5-dimethyl-2-cyclohexen-1-ylidene)pyrrolidinium iodide(80371-87-5)
• EPA Substance Registry System: N-(3-methoxy-5,5-dimethyl-2-cyclohexen-1-ylidene)pyrrolidinium iodide(80371-87-5)

Safety Data

• Hazardous Substances Data: 80371-87-5(Hazardous Substances Data)

Upstream product

• 126-81-8 dimedone 
• 3357-16-2 5,5-dimethyl-3-(1-pyrrolidinyl)-2-cyclohexen-1-one 
• 74-88-4 methyl iodide 

Downstream Products

• 69060-46-4 N-(3-methylthio-5,5-dimethyl-2-cyclohexen-1-ylidene)-N,N-dimethylammonium iodide 
• 80348-41-0 N-(5,5-dimethyl-3-thioxo-2-cyclohexenyl)-perhydro-1,4-thiazine 1-oxide 
• 80348-39-6 3-(4-aminophenylamino)-5,5-dimethyl-2-cyclohexene-1-thione 
• 80348-38-5 3-(4-bromophenylamino)-5,5-dimethyl-2-cyclohexene-1-thione 
• 80348-37-4 3-[2-(dimethylamino)ethylamino]-5,5-dimethylcyclohex-2-ene-1-thione 
• 80371-90-0 3-[(2-hydroxyethyl)amino]-5,5-dimethylcyclohex-2-ene-1-thione 
• 80348-40-9 3-dibutylamino-5m5-dimethyl-2-cyclohexene-1-thione 
• 70133-99-2 5,5-Dimethyl-3-amino-2-cyclohexenthion 
• 57966-11-7 3-N,N-dimethylamino-5,5-dimethyl-2-cyclohexene-1-thione 
• 70133-97-0 5,5-dimethyl-3-amino-2-cyclohexene-1-thione 
• 70134-02-0 3-(4-Methoxy-phenylamino)-5,5-dimethyl-cyclohex-2-enethione 
• 56268-55-4 5,5-dimethyl-3-phenylaminocyclohex-2-ene-1-thione 
• 69060-43-1 3-Ethylthio-5,5-dimethyl-2-cyclohexen-1-thion 
• 70133-98-1 5,5-Dimethyl-3-amino-2-cyclohexenthion 

Relevant articles and documents

Rigid core vinamidinium salts and their N,N′-rotamers

The power of proton magnetic resonance spectroscopy to unravel stereochemical details is amply demonstrated. O-Methylation of 3-methylamino-5,5-dimethyl-2-cylohexen-1-one (1a) produces stable diastereomers, (Z)- and (E)-N-(3-methoxy-5,5-dimethyl-2-cyclohexen-1-ylidine)-N-methylaminium iodide (2a). As predicted by computation and confirmed by spectroscopy, the (Z)-vinylogous imidate salt predominates. Reaction of 2a with primary and secondary amines furnished a number of vinamidinium salts, including N-(3-methylamino-5,5-dimethyl-2-cyclohexen-1-ylidene)-N-methylaminium iodide (3a). Two rotamers of 3a were identified and characterized. A substantial number of additional compounds 2 and 3 are included in the study.