70134-03-1Relevant academic research and scientific papers
α,β-UNSATURATED THIO COMPOUNDS. XXI. MECHANISM OF THE AMINOLYSIS OF 3-ALKOXY- AND 3-ALKYL-5,5-DIMETHYL-2-CYCLOHEXENE-L-THIONES
Usov, V. A.,Timokhina, L. V.,Turchaninov, V. K.,Taryashinov, D. S. D.,Voronkov, M. G.
, p. 1103 - 1108 (2007/10/02)
Experimental evidence has been obtained indicating the existence of a neutral intermediate with tetrahedral structure in the aminolysis of 2-alkoxy- and 3-alkylthio-2-cyclohexene-1-thiones.
α,β-UNSATURATED THIO COMPOUNDS. XIII.* HYDROTHIOLYSIS OF β-HETERO-SUBSTITUTED α,β-UNSATURATED IMMONIUM SALTS AT THE C=N(+) BOND - A GENERAL APPROACH TO THE SYNTHESIS OF FUNCTIONALLY SUBSTITUTED THIOKETONES
Usov, V. A.,Timokhina, L. V.,Zhagun, V. A.,Sidorkin, V. F.,Voronkov, M. G.
, p. 1623 - 1628 (2007/10/02)
The hydrothiolysis of immonium salts containing the Y-C=C-C=N(+) group takes place at the C=N(+) bond and not at the C-Y bond.This is consistent with the results from quantum-chemical calculations.On this basis a general approach was formulated to the synthesis of new types of organic sulfur compounds, i.e. β-alkoxy-, β-alkylthio-, and β-halogen-substituted α,β-unsaturated thioketones of the Y-C=C-C=S (Y=RO, RS, Hlg) type.
