70134-04-2Relevant articles and documents
POLYMERIZATION PROCESS WITH LIVING CHARACTERISTICS AND POLYMERS MADE THEREFROM
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, (2008/06/13)
A free radical polymerization process suitable for synthesizing polymers is disclosed. The process utilizes novel sulfur based chain transfer agents and is widely compatible over a range of monomers and reaction conditions. Novel polymers having low polydispersity and predictably specific polymer architecture and molecular weight are produced by the process. The polymers produced by the process are suitable for use as binders in automotive OEM and refinish coatings.
α,β-UNSATURATED THIO COMPOUNDS. XIII.* HYDROTHIOLYSIS OF β-HETERO-SUBSTITUTED α,β-UNSATURATED IMMONIUM SALTS AT THE C=N(+) BOND - A GENERAL APPROACH TO THE SYNTHESIS OF FUNCTIONALLY SUBSTITUTED THIOKETONES
Usov, V. A.,Timokhina, L. V.,Zhagun, V. A.,Sidorkin, V. F.,Voronkov, M. G.
, p. 1623 - 1628 (2007/10/02)
The hydrothiolysis of immonium salts containing the Y-C=C-C=N(+) group takes place at the C=N(+) bond and not at the C-Y bond.This is consistent with the results from quantum-chemical calculations.On this basis a general approach was formulated to the synthesis of new types of organic sulfur compounds, i.e. β-alkoxy-, β-alkylthio-, and β-halogen-substituted α,β-unsaturated thioketones of the Y-C=C-C=S (Y=RO, RS, Hlg) type.
