70134-06-4Relevant academic research and scientific papers
Hydrothiolysis of carbofunctional α,β-unsaturated sulfides as an approach to the synthesis of 1,7-dithiocarbonyl compounds
Timokhina,Sokol'nikova,Kanitskaya,Yashchenko,Toryashinova,Voronkov
, p. 1208 - 1212 (2007/10/03)
Bis(1-N,N-dimethylimmonio-3-phenylprop-2-en-3-yl) sulfide diperchlorate and (1-N,N-dimethyl-immonio-3-phenylprop-2-en-3-yl) (5,5-dimethyl-1- morpholiniocyclohex-2-en-3-yl) sulfide diperchlorate react with hydrogen sulfide giving rise to the corresponding
1,7-dithioxo systems. Synthetic routes to bis(5,5-dimethyl-3-thioxo-1-cyclohexenyl) sulfide
Timokhina,Panova,Kanitskaya,Sokol'nikova,Toryashinova,Voronkov
, p. 1655 - 1658 (2007/10/03)
Synthetic routes to bis(5,5-dimethyl-3-thioxo-1-cyclohexenyl) sulfide have been studied. The title compound can be obtained by reaction of 3-chloro-5,5-dimethyl-2-cyclohexenethione with sodium thiosulfate and by condensation of 3-mercapto-5,5-dimethyl-2-c
Ambifunctional Reactivity of 3-Trifloxypropeniminium Salts Towards Nucleophiles
Singer, Berndt,Maas, Gerhard
, p. 1683 - 1690 (2007/10/02)
Reaction of 3-trifloxypropeniminium salts 1 with nucleophiles may occur at carbon atoms C-1 or C-3.Hydrolysis of 1a-e leads to β-formylvinyl triflates 2 preferentially.The trifloxy group at C-3 is substituted in most cases by sulfur or nitrogen nucleophil
α,β-UNSATURATED THIO COMPOUNDS. XIII.* HYDROTHIOLYSIS OF β-HETERO-SUBSTITUTED α,β-UNSATURATED IMMONIUM SALTS AT THE C=N(+) BOND - A GENERAL APPROACH TO THE SYNTHESIS OF FUNCTIONALLY SUBSTITUTED THIOKETONES
Usov, V. A.,Timokhina, L. V.,Zhagun, V. A.,Sidorkin, V. F.,Voronkov, M. G.
, p. 1623 - 1628 (2007/10/02)
The hydrothiolysis of immonium salts containing the Y-C=C-C=N(+) group takes place at the C=N(+) bond and not at the C-Y bond.This is consistent with the results from quantum-chemical calculations.On this basis a general approach was formulated to the synthesis of new types of organic sulfur compounds, i.e. β-alkoxy-, β-alkylthio-, and β-halogen-substituted α,β-unsaturated thioketones of the Y-C=C-C=S (Y=RO, RS, Hlg) type.
