70150-86-6Relevant academic research and scientific papers
Kinetics and mechanism of oxirane formation by darzens condensation of ketones: Quantification of the electrophilicities of ketones
Li, Zhen,Jangra, Harish,Chen, Quan,Mayer, Peter,Ofial, Armin R.,Zipse, Hendrik,Mayr, Herbert
supporting information, p. 5500 - 5515 (2018/05/03)
The kinetics of epoxide formation by Darzens condensation of aliphatic ketones 1 with arylsulfonyl-substituted chloromethyl anions 2 (ArSO2CHCl-) have been determined photometrically in DMSO solution at 20 °C. The reactions proceed v
A new method for synthesis of alkylidene sulfones via direct alkylidenating reaction of ketones with Gem-dibromomethyl sulfones promoted by the Sm/SmI2 system in the presence of a catalytic amount of CrCl3
Liu,Wu,Zhang
, p. 47 - 52 (2007/10/03)
Alkylidene sulfones were prepared in moderate to good yields via direct alkylidenating reaction of ketones with geminal dibromomethyl sulfones promoted by Sm/SmI2 system in the presence of a catalytic amount of CrCl3 under mild conditions.
