70171-85-6Relevant academic research and scientific papers
Selective and efficient alcoholyses of allylic, secondary- and tertiary benzylic alcohols in the presence of iron(III)
Salehi, Peyman,Iranpoor, Nasser,Behbahani, Farahnaz Kargar
, p. 943 - 948 (1998)
An efficient and selective method for the conversion of allylic, secondary- and tertiary benzylic alcohols into their corresponding ethers in the presence of iron(III) as FeCl3 and Fe(ClO4)3 under solvolytic condition is d
Rapid probing of the reactivity of P450 monooxygenases from the CYP116B subfamily using a substrate-based method
Li, Ren-Jie,Xu, Jian-He,Yin, Yue-Cai,Wirth, Nicolas,Ren, Jiang-Meng,Zeng, Bu-Bing,Yu, Hui-Lei
, p. 8928 - 8934 (2016/10/13)
Developing a detailed understanding of the reactivity of self-sufficient Type IV P450 monooxygenases, four types of O-methylated substrates were designed as probes, including monoterpenes, cycloalkanes, aromatic compounds and steroids, and the efficiency of their oxyfunction was determined using a colorimetric assay which was based on the reaction between the enzymatic demethylation product, formaldehyde, and Purpald dye. The activity-based fingerprints of new P450RpMO, P450ArMO and P450CtMO (CYP116B members) indicated that CYP116B P450s preferentially oxidize substrates with aromatic components. Moreover, the hydroxylated products were detected based on the preference results. This rapid and efficient strategy, when coupled with GCMS, enables the exploration of the reactivity of other CYP116B members.
Applications of lanthanide trichloride hydrates prepared from mischmetall in Luche-type reduction
Lannou, Marie-Isabelle,Hélion, Florence,Namy, Jean-Louis
, p. 2707 - 2710 (2008/02/12)
An inexpensive alloy of light lanthanides, called Mischmetall, has been used in the preparation of a mixture of lanthanide trichloride hydrates. The use of this new type of material is described in Luche-type reductions. Georg Thieme Verlag Stuttgart.
Transetherification of allylic and benzylic ethers in the presence of ferric ion
Salehi, Peyman,Irandoost, Mohsen,Seddighi, Behnam,Kargar Behbahani, Farahnaz,Tahmasebi, Daryush Poor
, p. 1743 - 1747 (2007/10/03)
Alcoholysis of allylic, secondary and tertiary benzylic ethers is proceeded efficiently in the presence of catalytic amounts of ferric ion as anhydrous FeCl3 and Fe(ClO4)3.
