70197-04-5Relevant articles and documents
A solvent-free amidation of vinylogous esters via direct aziridination
McLaughlin, Emily C.,Shrestha, Anuska,Fletcher, Madison H.,Steinauer, Nathaniel S.,Shinn, Min Kyung,Shahid, Sabrina M.
, p. 5461 - 5463 (2013)
A microwave-mediated aziridination of α,β-unsaturated ketones and esters through the decomposition of ethyl azidoformate has been developed. When the same atom-economical reaction conditions are applied to cyclic vinylogous esters, N-functionalization at
Ring-opening Reactions of Some 1-Ethoxycarbonylaziridines with Acetic Acid in Cyclohexane
Takeuchi, Hiroshi,Koyama, Kikuhiko
, p. 121 - 126 (2007/10/02)
The formation of N(2-acetoxyalkyl)carbamates by acetolysis of 1-ethoxycarbonylaziridines in cyclohexane follows an A-2 mechanism where the rate is first order in the aziridine and second order in acetic acid.The regiospecificity of the formation and the r