70197-46-5Relevant academic research and scientific papers
Photo-induced electron-transfer reaction of aryl perfluoroalkanesulfonates with anilines
Chen, Qing-Yun,Li, Zhan-Ting
, p. 59 - 62 (2007/10/02)
Irradiation of mixtures of aryl perfluoroalkanesulfonates (RfSO3C6H4X-p, X = H, Cl and Me) (1) and aniline (2a), N,N-dimethylaniline (2b) or N,N-diethylaniline (2c) results in the formation of 2-coupling products 3 and 4-coupling products 4.However, in the reactions of 2b and 2c, in addition to 3 and 4, arenes 5 and N-methylaniline (6a) or N-ethylaniline (6b) are also detected.The presence of p-dinitrobenzene, But2NO and hydroquinone suppresses the reaction significantly.A photo-induced electron-transfer mechanism is proposed.
Photochemical Reaction of Diaryliodonium Salts with Dimethylaniline
Bi, Yubai,Neckers, Douglas C.
, p. 1139 - 1142 (2007/10/02)
A solution of 4,4'-dimethyldiphenyl iodonium tettrafluoroborate and N,N-dimethylaniline in acetonitrile is irradiated by UV light to give iodotoluene, toluene, 4,4'-methylenebis(N,N-dimethylaniline), crystal violet, methyl violet. KEY WORDS: 4,4'-dimethyldiuphenyl iodonium salt; N,N-dimethylaniline; 4,4'-methylenebis(N,N-dimethylaniline); crystal violet; methyl violet.
