702-48-7Relevant articles and documents
TMSCFX2(X = Cl, Br) as halofluorocarbene sources for the synthesis of halofluorocyclopropanes
Chen, Dingben,Fan, Zili,Huang, Ling,Gao, Kaili,Xiao, Pan,Ni, Chuanfa,Hu, Jinbo
, p. 319 - 322 (2021/01/25)
TMSCFX2 (X = Cl, Br; TMS = trimethylsilyl) have been developed as halofluorocarbene (CFX, X = Cl, Br) precursors for [2+1] cyclopropanation with alkenes. Structurally diverse halofluorocyclopropanes were obtained in good to excellent yields. It was found
Generation of Chlorofluorocarbene by Dehalogenation of Fluorotrichloromethane with Reduced Titanium. A New Synthesis of 1-Chloro-1-fluorocyclopropanes.
Dolbier, William R.,Burkholder, Conrad R.
, p. 6749 - 6752 (2007/10/02)
Reaction of fluorotrichloromethane with reduced titanium at 0 deg C produces chlorofluorocarbene which adds to alkenes, giving 1-chloro-1-fluorocyclopropanes in good yield